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Date of Issue : Feb 2002 1. IDENTIFICATION
General Product Name : ORGANIC PIGMENT BLUE Other Names : PIGMENT BLUE BLUE PHTHALOCYANINE ALPHA-FORM UN No. : N/A Dangerous Goods Class : None Allocated Subsidiary Risk : None Allocated Hazchem Code : N/A Pack Group : 0 EPG : N/A Poisons Schedule : N/A Uses : Various colouration of printing inks, lacquers, rubbers and resins, in paper colouring, textile printing.
1.1 Physical Description / Properties
Appearance : Blue powder, odourless. Formula : C32H16CuN8 Boiling Point : N/A deg C Melting Point : 480 deg C Vapour Pressure : N/A Specific Gravity : N/A (water = 1) Flash Point : N/A pH : 6.5 - 7.2 () Solubility in water : Insol g/l (25 deg C) Flammability Limits (as percentage volume in air) Lower Explosion Limit : N/A Upper Explosion Limit : N/A 1.2 Other Properties
Solubility in water = insoluble in water. Insoluble in fat. 1.3 Ingredients
2. HEALTH HAZARD INFORMATION
2.1 Health Effects - Acute Swallowed
Unlikely to be hazardous if swallowed. Eye
Non-irritant to rabbit eyes. Unlikely to cause eye irritation in humans. Skin
Non-irritant to rabbit skin. Unlikely to cause skin irritation in humans. Inhaled
High concentrations of dust may be irritant to the upper respiratory tract. 2.2 Health Effects - Chronic
Short-term tests and a consideration of the structure have shown that it is unlikely to be carcinogenic hazard to humans.
2.3 First Aid
Swallowed
Wash mouth out with water and give 200-300mls of water to drink. DO NOT induce vomiting. Obtain medical attention.
Eye
Irrigate with eyewash solution or clean water, holding eyelids apart, for at least 15 minutes. Obtain medical attention.
Skin
Remove contaminated clothing. Wash skin with water. If symptoms (irritation or blistering) occur obtain medical attention.
Inhaled
Remove patient from exposure. Obtain medical attention if ill effects occur.
First Aid Facilities
Ensure an eye bath and safety shower are available and ready for use.
2.5 Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
2.6 Toxicity Data
Oral LD50 = > 5000 mg/kg (Rat)
3. PRECAUTIONS FOR USE
3.1 Exposure Standards
No exposure limit has been established however the following for nuisance dust is recommended : TWA 10mg/m3
3.2 Engineering Controls
Ensure adequate ventilation to maintain exposure levels below standards
3.3 Personal Protection
Wear protective equipment to comply with good occulational hygiene practice. Respiratory - wear suitable repsiratory protective equipment if exposure to high levels of dust are likely. Eyes - wear eye protection, goggles/glasses. Skin - wear gloves. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using toilet facilities.
3.4 Flammability
Material is not flammable, but in common with many organic compounds in powder form it can produce flammable dust clouds in air. SAFE HANDLING INFORMATION
4.1 Storage / Transport
Take precautionary measures against static discharges. Keep containers tightly closed. Store in a cool, dry area away from direct heat. No special packaging or labelling requirements for storage or transport.
4.2 Packaging / Labelling UN No. N/A Class None Allocated Sub Risk None Allocated Hazchem Code N/A Pack Group 0 EPG No. N/A Shipping Name ORGANIC PIGMENT BLUE Hazard
Risk Phrases
Safety Phrases
4.3 Spills and Disposal
Spills
Avoid raising dust. Avoid contact with skin and eyes. Take precautionary measures against static dishcarges. Wear adequate protective equipment to minimise exposure to material.
Scoop up or sweep into a container for reuse or disposal. Wash spillage area clean. Do not allow untreated material to enter sewers, drains or water courses.
Disposal
Consult a local expert for advice on the disposal of this material. Ensure that disposal of this product is in compliance with local and national regulations.
4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion
In common with many organic compounds in powder form it can produce flammable dust clouds in air. Take precautionary measures against static discharges. During a fire prodct may emit gases of carbon dioxide, carbon monoxide, Nox and other toxic compounds.
Extinguishing Media
Use water spray or foam type extinguishers. Do not use carbon dioxide. Fire fighters should wear self-contained breathing apparatus in fire conditions. 5 OTHER INFORMATION
Other Information
Since inorganic pigment are generally insoluble in organic solvents; they are believed not to create any significant problem when released into the environment.
5.1 Contact Points
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The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use.
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